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An efficient strategy to separate nanoplastics from water using anisotropic magnetic Janus particles
Summary
Researchers developed amphiphilic magnetic Janus particles that selectively capture nanoplastics from water, achieving capture capacities of 10.3-19.2 mg/g — approximately 4-7 times higher than conventional magnetic particles. The anisotropic design leverages hydrophobic-hydrophilic surface asymmetry to enhance nanoplastic affinity, offering an efficient approach for drinking water treatment.
Nanoplastics (NPs) are emerging contaminants that threaten drinking water safety, and their selective removal remains challenging. Herein, amphiphilic magnetic Janus particles (MJPs) were synthesized to capture NPs from water, achieving high NP capture capacities (10.3-19.2 mg/g) approximately 4-7 times greater than those of previously reported materials. Hydrophobic interactions strongly drove NP capture, enabling MJPs to retain 80 % of their efficiency for selective NP removal, even in the presence of competing contaminants. Crucially, NP capture is governed by the confinement effect induced by the unique asymmetric structure of MJPs. Their negatively curved hydrophobic surface significantly enhances the interfacial activity and adsorption energy, resulting in a hydrophobic affinity that surpasses that of even more hydrophobic materials with positively curved surfaces. The applicability of MJPs was further evaluated for various NP types and verified in NP-contaminated drinking water, demonstrating their strong potential for capturing diverse NPs under real-water conditions. These findings highlight MJPs as an effective and novel solution for NP removal in water purification.