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Harnessing the power of metal-organic frameworks to develop microplastic fouling resistant forward osmosis membranes
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Microplastics are increasingly showing up in our water supplies, and current wastewater treatment methods struggle to filter them out efficiently. Scientists developed an improved water-filtering membrane using a special material that boosted water flow by 90% while resisting clogging from microplastics and other particles, meaning treatment plants could one day remove these tiny pollutants from water more effectively and for longer periods before needing replacement. This matters because reducing microplastics in our water systems could help limit our exposure to these particles, which have been linked to potential health concerns as they build up in the environment and food chain.
With the gradual increase of microplastics (MPs) in water and wastewater streams, it is imperative to investigate their removal using tertiary treatment systems to minimize and preferably prevent their entrance into aquatic environments. Forward osmosis (FO) is a non-pressurized membrane process with potential applications in MPs removal from wastewater. However, efficient application of FO systems relies on developing high-performance FO membranes with low fouling tendency. MPs are proven as emerging foulants in membrane systems, diminishing their performance and lifetime and this highlights the need to consider MP fouling in developing sustainable membranes. The current study focuses on a novel modification of thin film composite (TFC) FO membranes by MIL-53(Fe) as a water-stable and hydrophilic metal-organic framework. Experimental results demonstrated that the optimized FO membrane (0.2 wt% MIL-53(Fe)) achieved a significantly higher water flux (90% increase) with a 23% less reverse salt flux. The modified membrane also had significantly less flux decline in fouling experiments and higher flux recovery after physical cleaning compared to the control membrane affirming its higher antifouling efficiency. MIL-53(Fe) integration in the FO substrate proved to be a practical method for developing high-performance TFC FO membranes with improved antifouling properties against MPs and organic foulants.
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Evaluating the performance of the metal organic framework-based ultrafiltration membrane for nanoplastics removal
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Researchers created an advanced membrane filter using metal-organic framework nanoparticles that removed over 99% of nanoplastics from water while maintaining high water flow rates. The membrane resisted fouling and worked reliably across multiple cycles and different water conditions. This type of technology could improve wastewater treatment plants' ability to prevent nanoplastics from reaching drinking water supplies.
Microplastics-resistant FO membranes: Zwitterionic MOF nanoparticles for superior fouling control
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Researchers developed a new type of forward osmosis membrane modified with zwitterionic metal-organic framework nanoparticles to resist fouling by microplastics. The modified membranes showed a 73 percent improvement in water-attracting properties and only a 17 percent decline in water flow during fouling tests, compared to 60 percent for unmodified membranes. The technology could improve the efficiency of water treatment systems that need to handle microplastic-contaminated water.
Defect-engineered metal organic framework thin film nanocomposite membranes for enhanced forward osmosis performance and microplastic antifouling
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Researchers engineered a new type of water filtration membrane by embedding specially designed metal-organic framework (MOF) particles into a thin film, achieving a three-fold increase in water flow rate while also becoming significantly more resistant to fouling by microplastics compared to standard membranes. The MOF particles were given controlled structural defects that created additional water transport pathways and made the membrane surface more water-attracting, reducing plastic particle adhesion. More efficient, fouling-resistant membranes could improve the viability of advanced water treatment systems for removing microplastics.
Dual metal-organic framework composite – Polyethersulfone hybrid hollow fiber membranes for effective elimination of microplastics and toxic contaminants from wastewater via ultrafiltration
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Scientists developed a new water-filtering material that can remove up to 97% of microplastics, along with toxic dyes and heavy metals like lead and mercury, from contaminated water. This matters because current water treatment methods often struggle to catch these tiny plastic particles and pollutants, which can build up in our bodies over time; this new filter could offer a cheaper, more effective way to clean drinking water and protect public health.
Fabrication of dual-charged MOF-based ultrafiltration membrane to remove charged nanoplastics from wastewater
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Researchers developed a new type of water filter membrane that can remove over 99% of nanoplastics from wastewater while maintaining high water flow. The membrane uses metal-organic framework nanoparticles that repel plastic particles through electrical charges and physical filtering. This technology could help prevent nanoplastics, which are too small for conventional filters, from reaching drinking water sources.
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