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Forensic Assessment of Textile Fibers Using Micro FTIR-ATR Spectroscopy

Preprints.org 2023 1 citation ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 30 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Samara Alves Testoni, Samara Alves Testoni, Rafael Scorsatto Ortiz Kristiane de Cássia Mariotti, Flavio Anastácio de Oliveira Camargo, Flavio Anastácio de Oliveira Camargo, Flavio Anastácio de Oliveira Camargo, Kristiane de Cássia Mariotti, Rafael Scorsatto Ortiz

Summary

This study evaluated micro Fourier transform infrared spectroscopy for identifying textile fibers in forensic investigations, finding it can characterize fiber composition even from very small samples. The same technique is widely used for identifying microplastic polymer types in environmental samples.

Polymers

Forensic assessments may involve the sampling of textile fibers when examining crime scenes. The need to characterize and identify those fibers is crucial as they can provide extensive information relating to a crime, linking a suspect to a location. Fibers in particular may contain issues in terms of both size and quantity of sample, and micro Fourier transform Infrared in attenuated total reflectance mode (micro FTIR-ATR) spectroscopy presents a non-destructive method to identify those fibers. In this study we carried out a rapid forensic assessment via micro FTIR-ATR of sixty textile fibers recovered from twenty white fabrics relying on tape lifting method, in order to discriminate those materials. Two dimensional principal component analysis and radar chart were applied to enhance the visual comparison of the fibers. Results of infrared spectra revealed that the technique allows the discrimination of textile fibers according to their spectral composition (cellulose, polyamide, polyester, or mixture of these composites) and to some characteristics, as number and width of peaks, peak position according to the wavenumber, absorbance index related to peak sharpness, etc. The technique was deemed useful in the forensic assessment of the fibers, presenting rapid and enlightening results.

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