0
Article ? AI-assigned paper type based on the abstract. Classification may not be perfect — flag errors using the feedback button. Tier 2 ? Original research — experimental, observational, or case-control study. Direct primary evidence. Human Health Effects Marine & Wildlife Sign in to save

Legacy and Emerging Plasticizers and Stabilizers in PVC Floorings: Impacts of an Industrial Transition and Recycling

2023 2 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Helene Wiesinger, Christophe Bleuler, Christophe Bleuler, Verena Christen, Philippe Favreau, Stefanie Hellweg, Miriam Langer, Roxane Pasquettaz, Andreas Schönborn, Zhanyun Wang

Summary

This study systematically analysed 151 new PVC floor coverings on the Swiss market, finding that 16% still contained regulated hazardous chemicals — mainly lead and DEHP — above legal thresholds, likely introduced via recycled PVC. A further 29% contained alternative plasticizers not yet subject to the same scrutiny but detected in bioassays for cytotoxicity and endocrine disruption. The findings reveal that recycling of PVC can inadvertently reintroduce banned chemicals into new products, posing indoor exposure and health risks, and that some replacement plasticizers may themselves warrant toxicological concern.

Polymers
Body Systems

Hazardous chemicals in building and construction plastics can lead to significant indoor exposure, health risks, and contamination of recycled materials. We systematically sample new PVC floorings on the Swiss market (n=151). We conduct elemental analysis using XRF, targeted and sus-pect GC MS analysis of ortho phthalates and alternative plasticizers, and bioassay tests for cytotoxicity, oxidative stress, and endocrine, mutagenic, and genotoxic activities (for selected samples). Surprisingly, 16% of the samples contain regulated chemicals above 0.1 weight%, mainly lead and bis(2-ethylhexyl) phthalate (DEHP). Their presence is likely linked with the use of recycled PVC in new floorings, highlighting that uncontrolled recycling can delay the phase-out of hazardous chemicals. Furthermore, 29% of the samples contain ortho-phthalates besides DEHP (mainly diisononyl and diisodecyl phthalates, DiNP and DiDP) above 0.1 weight%, and 17% of the 85 tested samples cause certain adverse biological effects. Together, they make up an additional 35% of samples of potential concern. Moreover, both suspect screening and bioassay results indicate the presence of additional (potentially) hazardous substances, including emerging alternative plasticizers. Overall, our study highlights the urgent need for accelerating the phase-out of hazardous substances and enhancing transparency of chemical compositions in plastics to protect human and ecosystem health and enable the transition to a safe and sustainable circular economy.

Share this paper