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Unlocking the Potential of MOFs for Waste Plastic Resource Utilization and Microplastic Pollution Control

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This review examines the potential of metal-organic frameworks (MOFs) — a class of highly porous, engineered materials — to serve as catalysts for both breaking down microplastic pollution and converting waste plastic into valuable chemical feedstocks. MOFs offer tunable structures and large surface areas that make them attractive for both degradation and upcycling applications. The review positions MOF-enabled catalysis as a tool for transitioning toward a circular plastics economy where waste plastic becomes a resource rather than a pollutant.

The global plastic waste crisis urgently calls for innovative strategies that move beyond conventional disposal methods. Against this backdrop, establishing a circular pathway for plastic waste—effectively converting end-of-life products into valuable resources—has become a critical objective for sustainable development. Metal–organic frameworks (MOFs) have emerged as a revolutionary catalytic platform, offering unique advantages such as structural tunability, ultrahigh surface area, and precisely designable active sites, thereby opening new possibilities for achieving this goal. This review highlights the great potential of MOF-based catalysts in addressing key challenges during plastic valorization and explores their role as ideal drivers for such a circular plastic pathway. It systematically summarizes synthesis strategies for MOFs and recent advances in their catalytic applications, covering pathways for converting plastics into high-value monomers or chemicals, as well as efficient microplastic degradation. The core objective is to demonstrate how MOF-enabled catalysis can bridge waste plastics and renewable resources, thereby providing strategic support for building a circular plastic economy.

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MOF Catalysts for Plastic Depolymerization

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This review highlights how metal-organic frameworks (MOFs), a class of highly customizable porous materials, can be used as catalysts to break down plastic waste into reusable chemical building blocks. MOFs offer advantages over traditional recycling methods because they can be precisely designed to target specific plastic types. While focused on plastic waste solutions rather than health effects, this technology could help reduce the amount of plastic that eventually breaks down into microplastics in the environment.

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A review on microplastics degradation with MOF: Mechanism and action

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This review examines how metal-organic frameworks (MOFs) can be used to break down microplastics through various mechanisms including hydrolysis, oxidation, and photodegradation. Researchers found that MOFs' large surface area and tunable pore sizes make them well-suited for capturing and degrading microplastic particles. While the field is still in its early stages, the study suggests that MOF-based approaches could represent a significant step forward in addressing microplastic pollution.

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