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Chemical recycling of polyolefins: a closed-loop cycle of waste to olefins

National Science Review 2023 88 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Liang Zou, Run Xu, Hui Wang, Zhiqiang Wang, Yuhan Sun, Mingfeng Li

Summary

This review examines chemical recycling methods that can convert polyolefin plastic waste back into olefins, creating a true closed-loop cycle. Researchers describe how pyrolysis, including thermal, catalytic, and solvent-based approaches, breaks down plastic waste into reusable chemical building blocks. The study suggests that chemical recycling holds significant potential for addressing plastic pollution by turning waste into valuable raw materials rather than sending it to landfills.

The unsuitable disposal of plastic wastes has caused serious environmental pollution, and finding a green manner to address this problem has aroused wide concern. Plastic wastes, especially polyolefin wastes, are rich in carbon and hydrogen, and chemical recycling shows distinct advantages in their conversion into olefins and realizes a closed-loop cycling of plastic wastes. Plastic wastes should be labeled before disposal. The necessity for, and methods of, pretreatment are introduced in this paper and the whole recycling process of polyolefin wastes is also summarized. As the core technology pyrolysis, including thermal, catalytic and solvolysis processes, is introduced in detail due to its potential for future development. We also briefly describe the feasible strategies of pyrolytic oil refining and life cycle assessment of the chemical recycling process. In addition, suggestions and perspectives concerning the industrial improvement of polyolefin chemical recycling are proposed.

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