Hydro-geomorphic perspectives on microplastic distribution in freshwater river systems: A critical review

Freshwater river systems are commonly defined as the main transport paths of microplastics (MP) from land into the seas. A shift in research interest from oceans to rivers can be observed, as a large number of i) case studies, ii) review papers and iii) experimental studies in this field have been published recently. Still, studies often lack an in-depth consideration of quantification, as units are mostly based on item numbers. Spatiotemporal aspects are often neglected. Transport paths linking MP sources and sinks in the environment are insufficiently understood and only recently the awareness increased that sustainable management of the MP pollution cannot be addressed without a sound knowledge of water- and sediment-driven MP transport. Within this review paper, we therefore i) reviewed 92 MP case-studies, with a special focus on spatiotemporal aspects and ii) gathered and compared global load-estimation data from these studies. We then outlined the key processes determining MP movement in rivers on the basis of existing laboratory experiments and theoretical approaches. A procedure to effectively compare units of MP in the water column and in riverine sediments was developed on the basis of i) an extensive MP-dataset in German waterways and ii) suspended sediment concentrations (SSC) of nearest monitoring stations of the German water and shipping authority. Our analysis indicates that relating MP in water samples to SSC reduces the often stated large difference between MP concentrations in the water column and bed sediments and therefore relativizes the importance of river beds as a major "MP sink". As for a quantification of MP fluxes, the use of MP masses as unit is crucial, we applied an approach to convert MP items to masses with the help of i) a power-law distribution of MP-particle size, triangular distributions of ii) form-ratios and iii) polymer densities. An evaluation with an own, extensive dataset of MP-particles showed reasonable results. Therefore, we translated global load data from item numbers to mass values for further analysis. Values were within a reasonable range, especially when considering the respective catchment size of each river at the sampling site.