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Toughening Enhancement Mechanism and Performance Optimization of Castor-Oil-Based Polyurethane Cross-Linked Modified Polybutylene Adipate/Terephthalate Composites
Summary
This materials science study improved the mechanical properties of the biodegradable plastic PBAT by cross-linking it with castor oil-based polyurethane. The best formulation increased tensile strength by 86% and elongation at break by 70% compared to pure PBAT, enhancing its potential as a biodegradable alternative to conventional plastic films.
In this study, polyol castor oil (CO) and toluene-2,4-diisocyanate (TDI) were selected to modify PBAT, and castor-oil-based polyurethane (COP) was produced in a PBAT matrix using melt-blending and hot-pressing technology to study the effect of network cross-linking structure on various properties of bio-based polyester PBAT, aiming to introduce CO and TDI to improve the mechanical properties of composite materials. The results showed that when the total addition of CO and TDI was 15%, and the ratio of the hydroxyl group of CO to the isocyanate group of TDI was 1:1, the mechanical properties were the best. The tensile strength of the composite was 86.19% higher than that of pure PBAT, the elongation at break was 70.09% higher than that of PBAT, and the glass transition temperature was 7.82 °C higher than that of pure PBAT. Therefore, the composite modification of PBAT by CO and TDI can effectively improve the heat resistance and mechanical properties of PBAT-based composites.
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