Microplastic removal in batch and dynamic coagulation-flocculation-sedimentation systems is controlled by floc size

Most studies examining the removal of microplastics (MPs) during controlled bench-scale trials have applied high coagulant dosages, which are characteristic of sweep flocculation. As such the impact of other typical operating conditions remains largely unknown. The use of bench-scale jar testing is ubiquitous in the literature, however the hydrodynamics of a batch-type approach bear little resemblance to full-scale treatment processes. In this study, a range of microplastics sizes and types were employed to assess their removal via conventional jar tests as well as to compare results to a continuous-flow bench-scale system. Jar tests were performed to identify pH values and alum dosages that are optimal for MP reduction when considering a range of coagulation conditions. The production of large and readily settling aluminum hydroxide (Al(OH)) floc represented the dominant condition driving MPs removal. However, total MP removal was observed to be lower during continuous-flow trials when compared to jar tests, suggesting that direct extrapolation of results from jar tests may overpredict performance observed at full-scale. Irrespective of microplastic type and size, strong correlations were observed between MP concentration and turbidity reduction, indicating that turbidity may potentially serve as a very useful surrogate. Significant correlations were observed when comparing both floc size, especially 90th percentile floc diameter, and concentration of floc >100 μm to the reduction of MPs.