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Effect of surfactant concentration on the synthesis of hydrogel microbeads using the emulsion polymerization process for acrylamide/acrylic acid copolymers

Springer Link (Chiba Institute of Technology) 2025 Score: 38 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Nutthakritta Philaiwan, Nutthakritta Philaiwan, Nutthakritta Philaiwan, Nutthakritta Philaiwan, Siriporn Pranee, Siriporn Pranee, Siriporn Pranee, Siriporn Pranee, Samitthichai Seeyangnok Samitthichai Seeyangnok

Summary

Researchers synthesized hydrogel microbeads from acrylamide/acrylic acid copolymers via emulsion polymerization as a potential biodegradable alternative to the microplastic microbeads commonly found in personal care products. They found that increasing surfactant concentration produced smaller, more homogeneous particles but reduced swelling capacity, characterizing the products by SEM and FTIR.

Personal care and cosmetic goods frequently contain microplastic particles, specifically microbeads with an average diameter of 250 mm, which make up about 5% of the product weight. Pollution may result from these microbeads’ persistence in the environment. The goal of this study is to use emulsion polymerization to synthesize hydrogel microbeads from copolymers based on acrylamide. The study focuses into the surfactant concentrations affects swelling behavior and particle size. Scanning electron microscopy (SEM) is used to assess particle size and determine the swelling ratio, and Fourier transform infrared spectroscopy (FTIR) is used for chemical analysis. The results show that while swelling capacity decreases with increasing surfactant concentration, smaller and more homogeneous particles are produced. The result provides a systematic method to creating microbeads with adjustable characteristics. Additionally, the chosen synthesis materials have the potential to sustainably minimize water contamination and lessen the accumulation of hazardous residues.

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