Influence of magnetite and its weathering originated maghemite and hematite minerals on sedimentation and transport of nanoplastics in the aqueous and subsurface environments

Persistent nanoplastics (NPs) and their interaction with ubiquitous iron oxide minerals (IOMs) require a detailed understanding to dictate NPs fate and transport in aqueous and subsurface environments. Current study emphasizes on understanding nanoplastics (NPs) interaction with magnetite, and its weathering-originated mineral colloids, i.e., maghemite and hematite under varying environmental conditions (pH, humic acid, ionic strength and water matrix). Results showed that the higher surface hydroxyl group, smaller particle size, and positive surface charge of magnetite led to maximum NPs sorption (805.8 mg/g) in comparison to maghemite (602 mg/g) and hematite (384.3 mg/g). Charge distribution and sedimentation kinetic studies in bimodal systems showed enhanced coagulation in magnetite-NPs system. FTIR and XPS analysis of NPs-IOMs reaction precipitate revealed the vital role of surface functionality in their interaction. Column experiments revealed higher NPs retention in IOMs-coated quartz sand than bare quartz sand. Further, in river water (RW), magnetite-coated sand has shown maximum NPs retention (>80 %) than maghemite (62 %) and hematite (52 %), suggesting limited NPs mobility in the presence of magnetite in subsurface conditions. These findings elucidated the dependence of NPs fate on IOMs in freshwater systems and illustrated IOMs impact on NPs mobility in the subsurface porous environment.