Aging and characterization of disposable polypropylene plastic cups based microplastics and its adsorption for methylene blue

Microplastics (MPs) as emerging pollutants are of increasing concern, due to their ubiquitous, uncertain, and complex environmental impacts. Different from the standard spherical MPs without additives, here polypropylene microplastics (PP-MPs) in flake derived from the disposable plastic cup in food-grade in daily life were studied. The characterization of PP-MPs demonstrated that the carbonyl index represented the aging degree was enhanced from 0.26 significantly to 0.82 after 10 days, and the aging process fitted well with pseudo-first-order kinetic. Moreover, the crystallinity degree, polarity and surface negative charges were enhanced, while the hydrophobicity was decreased. The adsorption behavior of PP-MPs toward methylene blue (MB), and the impacts of various pHs, salinities, and humic acid in aquatic environments were also explored. The pseudo-second-order kinetic, Henry and Sips isotherm models provided a good correlation with the experimental data, indicating that the rate-limiting step was closely related with the complex surface adsorption, and the hydrophobic partitioning, polar interaction, electrostatic attraction, and hydrogen bonding were possibly involved in the adsorption. These exhaustive experiments aim to provide a theoretical basis for assessing and better understanding the environmental behavior of disposable PP plastic cups in nature.