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Enzymatic bulk synthesis, characterization, rheology, and biodegradability of biobased 2,5-bis(hydroxymethyl)furan polyesters

Green Chemistry 2024 19 citations

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Researchers synthesized biobased polyesters from 2,5-bis(hydroxymethyl)furan using an enzymatic process rather than traditional chemical methods. They found that the thermal, mechanical, and flow properties of the resulting polymers could be tuned by varying the structural composition. The study also showed that these compositional changes influenced how quickly the material biodegrades, pointing toward customizable bioplastics.

BHMF-based polyesters are synthesized via enzymatic bulk polymerization. The thermal, mechanical and rheological properties can be tuned by varying the structural composition of the polymer, which also influences the biodegradation rate.

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