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Particle size and co-presence of PFOA alter the transport of microplastics in saturated natural sediment
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Researchers investigated how microplastic particle size and the co-presence of the contaminant PFOA affect microplastic transport through natural sediment. The study found that smaller microplastics were more mobile, while PFOA altered transport dynamics, indicating that co-occurring pollutants can influence how microplastics move through environmental substrates.
The transport of microplastics (MPs) with two different sizes in the absence and presence of perfluorooctanoic acid (PFOA) in sediment were systematically investigated in this study. Smaller size of MPs exhibited great transport mobility, while larger size of MPs significantly retained in sediment via electrostatic repulsion and straining mechanisms. MPs transport was insignificantly affected by influent pH values (4.7 and 6.0), likely due to the great buffer capacity of sediment. Effect of PFOA on MPs transport in sediment varied with MPs size and influent pH conditions. PFOA induced more negatively charged MPs surface and greater MPs transport at influent pH of 4.7, and this accelerating effect was more significant for MPs with greater size. In contrast, PFOA have little effect on the transport of both sized MPs at influent pH of 6.0. This work improved our understanding of MPs transport with the co-presence of PFOA in sediment environment.
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Researchers reviewed the key factors that control how micro- and nanoplastics move through porous media such as soil and sediment, and how they affect the transport of co-occurring pollutants. They found that microplastics can either facilitate or inhibit the movement of other contaminants depending on particle properties and environmental conditions. The review emphasizes the need to better understand these co-transport dynamics for predicting the environmental fate of plastic pollution.
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