We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Sorption of Polycyclic Aromatic Sulfur Heterocycles (PASH) on Nylon Microplastics at Environmentally Relevant Concentrations
Summary
Researchers investigated the sorption of polycyclic aromatic sulfur heterocycles (PASH), a class of persistent organic pollutants, onto nylon microplastics, characterizing adsorption kinetics and capacity. Nylon showed significant PASH sorption, suggesting that microplastics can act as vectors for these contaminants in aquatic environments.
Microplastics have garnered an infamous reputation as a sorbate for many concerning environmental pollutants and as a delivery vehicle for the aquatic food chain through the ingestion of these contaminated small particulates. While sorption mechanisms have been extensively studied for polycyclic aromatic hydrocarbons, polycyclic aromatic sulfur heterocycles (PASHs) have not been investigated, partly due to their low concentrations in aquatic ecosystems. Herein, an analytical methodology is presented for the analysis of dibenzothiophene, benzo[b]naphtho[1,2-b]thiophene, benzo[b]naphtho[2,1-b]thiophene, benzo[b]naphtho[2,3-b]thiophene, chryseno[4,5-bcd]thiophene and dinaphtho[1,2-b:1',2'-d]thiophene at relevant environmental concentrations based on solid phase extraction and high-performance liquid chromatography. The sorption uptake behavior and the sorption kinetics of the three benzo[b]napthothiophene isomers were then investigated on nylon microplastics to provide original information on their environmental fate and avoid human contamination through the food chain. The obtained information might also prove relevant to the development of successful remediation approaches for aquatic ecosystems.
Sign in to start a discussion.
More Papers Like This
Adsorption behavior of aniline pollutant on polystyrene microplastics
Researchers investigated how polystyrene microplastics adsorb the pollutant aniline in aquatic environments, finding that particle size, temperature, and solution chemistry significantly influence adsorption behavior, highlighting microplastics' role as carriers of toxic organic compounds.
Sorption of Pyrene and Fluoranthene onto Common Microplastics Under Freshwater Conditions
Researchers investigated how two common polycyclic aromatic hydrocarbons, pyrene and fluoranthene, bind to six different types of microplastic polymers under freshwater conditions. The study found significant differences in sorption capacity across polymer types, confirming that microplastics can act as vectors for transporting harmful organic pollutants through aquatic environments.
Adsorption of perfluoroalkyl substances on polyamide microplastics: Effect of sorbent and influence of environmental factors
Researchers studied how perfluoroalkyl substances (PFAS), a group of persistent industrial chemicals, bind to polyamide microplastics in water. They found that smaller microplastic particles absorbed dramatically more PFAS than larger ones, and that water chemistry conditions like pH and salinity influenced the process. The findings suggest microplastics can concentrate harmful chemicals and potentially increase human and wildlife exposure to PFAS in contaminated environments.
Potential of Adsorption of Diverse Environmental Contaminants onto Microplastics
Researchers assessed the ability of four common types of microplastics to adsorb hazardous environmental contaminants including dyes and heavy metals. They found that dyes were adsorbed through physical processes while heavy metal adsorption varied by plastic type, with polystyrene showing the highest capacity for certain metals. The study confirms that microplastics can act as vectors for diverse pollutants, potentially increasing the environmental mobility and bioavailability of toxic substances.
Comparative evaluation of sorption kinetics and isotherms of pyrene onto microplastics
This study compared how quickly and how much pyrene — a common polycyclic aromatic hydrocarbon — is absorbed by different types of microplastics in aquatic environments. The results indicate that microplastic polymer type significantly affects how well it concentrates and potentially transports toxic organic chemicals.