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Leaching hazards of tire wear particles in hydrothermal treatment of sludge: Exploring molecular composition, transformation mechanism, and ecological effects of tire wear particle-derived compounds
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When sewage sludge containing tire wear particles was treated with high heat and pressure, the process accelerated the release of harmful chemicals from the tire rubber into the liquid byproduct. Researchers identified 144 different chemical compounds leaching from the tire particles, many of which were toxic to aquatic organisms and plants -- highlighting how waste treatment processes can inadvertently spread tire-derived microplastic pollution.
Tire wear particles (TWPs) are considered a significant contributor of microplastics (MPs) in the sludge during heavy rainfall events. Numerous studies have shown that hydrothermal treatment (HT) of sludge can accelerate the leaching of MP-derived compound into hydrothermal liquid, thus impairing the performance of subsequent anaerobic digestion and the quality of the hydrothermal liquid fertilizer. However, the leaching behavior of TWPs in the HT of sludge remains inadequately explored. This study examined the molecular composition of TWP-derived compounds and transformation pathways of representative tire-related additives under different hydrothermal temperatures using liquid chromatography-tandem mass spectrometry (LC-MS/MS) combined with mass difference analysis. The acute toxicity and phytotoxicity of TWP leachates were assessed using Vibrio qinghaiensis Q67 and rice hydroponics experiments. The results indicated that elevating the hydrothermal temperature not only amplified the leaching behavior of TWPs but also enhanced the chemical complexity of the TWP leachate. Utilizing both suspect and non-target screenings, a total of 144 compounds were identified as additives, including N-(1,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine (6-PDD), hexa(methoxymethyl)melamine (HMMM), dibutyl phthalate (DBP). These additives underwent various reactions, such as desaturation, acetylation, and other reactions, leading to the formation of different transformation products (TPs). Moreover, certain additives, including caprolactam and 2,2,6,6-tetramethyl-4-piperidinol, demonstrated the potential to form conjugate products with amino acids or Maillard products. Meanwhile, TWP-derived compounds showed significant acute toxicity and detrimental effects on plant growth. This study systematically investigated the environmental fate of TWPs and their derived compounds during the HT of sludge, offering novel insights into the intricate interactions between the micropollutants and dissolved organic matter (DOM) in sludge.
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Researchers analyzed the chemical composition and biofilm communities forming on tire-wear particles compared to other microplastic types, finding that tire wear particles support distinct microbial assemblages. The unique surface chemistry of tire wear particles may promote the attachment of pathogens and toxin-producing microorganisms.
Tire wear particles in different water environments: occurrence, behavior, and biological effects—a review and perspectives
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This review examines tire wear particles, a major but often overlooked source of microplastics in water environments. Tire particles release toxic chemicals as they break down in water and can harm aquatic organisms, but most research has focused only on the chemical leachate rather than the particles themselves. Since tire wear contributes a large share of total microplastic pollution, understanding its full impact on water ecosystems and the food chain is important for human health.
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This review of 30 studies shows that worn tires release tiny particles, chemicals, and microplastics into air, water, and soil, some of which are known health hazards. As these particles are already turning up in the environment, understanding how they spread matters for reducing our exposure. The researchers also point to recycling methods that could help cut this pollution.
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