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Photoaging processes and mechanisms of polyolefin microplastics
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This perspective paper examines how microplastics in natural water photoage under UV irradiation via reactive oxygen species generation, breaking down polymer bonds, and explores how dissolved organic matter may accelerate or alter these aging pathways. Understanding photoaging is critical because it fragments plastics into smaller and more biologically available nanoplastics while releasing toxic chemical additives into aquatic ecosystems.
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Researchers discovered that biofilms — thin layers of microbes that naturally colonize plastic surfaces in water — actually slow down the light-driven breakdown of microplastics by blocking UV radiation and reducing the reactive oxygen species that degrade the plastic, suggesting that real-world plastics may persist longer in nature than lab studies predict.
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This chapter detailed the photodegradation mechanisms by which UV radiation breaks polymer chains in common plastics, progressively generating smaller microplastic and nanoplastic fragments without eliminating the material from the environment. Understanding these photochemical pathways clarifies why sunlight-exposed plastic waste — in oceans, soils, and landfills — continuously generates new microplastic particles that accumulate in ecosystems and food chains.
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