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What is the most effective analytical method for quantification and identification of microplastics in contaminated soils?

Environmental Geochemistry and Health 2024 10 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Maura Gabriela da Silva Brochado, Bruno Gomes de Noronha, Alessandro da Costa Lima, Allana Grecco Guedes, Renê Chagas da Silva, Denise Cunha Fernandes dos Santos Dias, Kássio Ferreira Mendes

Summary

Researchers compared four analytical methods for detecting microplastics in agricultural soils: near-infrared spectroscopy, scanning electron microscopy, multispectral analysis, and X-ray diffraction. They found that near-infrared spectroscopy and multispectral analysis were the most sensitive and accurate, while X-ray diffraction could only detect microplastics at very high concentrations. The study provides practical guidance for selecting the most effective technique for monitoring microplastic contamination in farmland soils.

The increasing concern over microplastics (MPs) contamination in agricultural soils due to excessive plastic use is a worldwide concern. The objective of this study was to determine which analytical technique is most effective for the analysis of MPs in agricultural soils. Near-infrared spectroscopy (NIR), scanning electron microscopy (SEM), multispectral analysis, and X-ray diffraction were used to analyze sections of clay soil containing varying percentages of virgin white MPs from 0 to 100%. X-ray analysis only detected MPs at high concentrations (20%). However, NIR at 2.300 nm and multispectral analysis at 395 nm demonstrated greater accuracy and sensitivity in distinguishing between all MPs levels. SEM revealed that MPs have an amorphous structure that is distinct from crystalline soil, potentially influencing their interactions with other soil constituents. These findings highlight the value of NIR and multispectral analysis in accurately identifying and measuring MPs in soil. Efficient management plans rely on increased awareness of MPs' environmental impact.

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