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Enlarging effects of microplastics on adsorption, desorption and bioaccessibility of chlorinated organophosphorus flame retardants in landfill soil particle-size fractions
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Researchers studied how microplastics affect the behavior of chlorinated flame retardant chemicals in landfill soils, including their tendency to be absorbed by the human body during digestion. They found that adding microplastics increased both the retention of these chemicals in soil and their bioaccessibility, raising potential health risks for people exposed to contaminated landfill material. The study presents the first evidence that microplastics can amplify human exposure to toxic flame retardants in landfill settings.
Chlorinated organophosphorus flame retardants (Cl-OPFRs) and microplastics (MPs) are emerging pollutants in landfills, but their synergistic behaviors and triggering risks were rarely focused on, impeding the resource utilization of landfill soils. This study systematically investigated the adsorption/desorption behaviors, bioaccessibility and human health risks of Cl-OPFRs in landfill soil particle-size fractions coexisted with MPs under simulated gastrointestinal conditions. The results showed that the adsorption capacity and bioaccessibility of Cl-OPFRs in humus soil were higher than that in subsoil. MPs promoted the adsorption of tris(1-chloro-2-methylethyl) phosphate (TCPP) and tris(1,3-dichloro-2-propyl) phosphate (TDCPP) in landfill soils by up to 34.6 % and 34.1 % respectively, but inhibited the adsorption of tris(2-chloroethyl) phosphate (TCEP) by up to 43.6 %. The bioaccessibility of Cl-OPFRs in landfill soils was positively correlated with MPs addition ratio but negatively correlated with the K of Cl-OPFRs, soil organic matter and particle size. MPs addition increased the residual concentration of Cl-OPFRs and significantly increased the bioaccessibility of TCEP and TDCPP by up to 33.1 % in landfill soils, resulting in higher carcinogenic and noncarcinogenic risks. The study presents the first series of the combined behavior and effects of MPs and Cl-OPFRs in landfill soils, and provides a theoretical reference for landfill risk management.
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Unveiling the Modulatory Role of Microplastics in the Release of Chlorinated Organophosphorus Flame Retardants from Landfill Soils
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Microplastics and toxic flame retardants (Cl-OPFRs) often co-exist in landfill soils, and this study reveals that the plastics actually slow down how quickly the chemicals are released into the surrounding environment. The type of plastic matters: polar plastics like PVC and nylon hold onto flame retardants through electrostatic attraction, while non-polar plastics like polyethylene and polypropylene rely on hydrophobic interactions. This finding is important for understanding whether microplastics in landfills are reducing or delaying chemical risks — and whether they might eventually release concentrated bursts of toxic compounds.
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