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Beyond Removal: A Critical Review of Microplastic Mass Flux, In-Plant Transformation, and Elimination in WWTPs
Summary
This review of existing research found that water treatment plants can remove 60-90% of microplastics (tiny plastic particles) from wastewater, with advanced systems removing over 95%. However, these plastic particles don't disappear—they mostly end up in sewage sludge that's often used as fertilizer, meaning the microplastics can still enter the environment and potentially our food chain. Better elimination methods are needed to actually destroy these particles rather than just moving them around.
Microplastics (MPs) persist in wastewater treatment systems owing to their durability and mobility. As critical interception points, wastewater treatment plants (WWTPs) receive MPs from diverse domestic and industrial sources. This review synthesizes peer-reviewed studies (2009–2026) to evaluate MP mass flux, in-plant transformation, and elimination across primary, secondary, and tertiary stages. While conventional processes typically remove 60–90% of MPs, advanced tertiary technologies, such as membrane bioreactors and rapid sand filtration, can achieve efficiencies exceeding 95%. The fate of MPs is governed by density-driven settling and biological aggregation; however, the significant accumulation of MPs in sewage sludge represents a critical pathway for environmental re-entry. This review highlights key knowledge gaps, including inconsistent analytical methodologies, evidence of in-plant fragmentation generating nanoplastics (NPs), and uncertainties regarding full-scale mass flows. Furthermore, the review synthesizes mass flux data to clarify the partitioning of MPs between the effluent and sludge, identifying biosolids as a primary sink. The review concludes by proposing a transition from physical separation to elimination technologies (e.g., AOPs), alongside standardized monitoring and regulatory frameworks, to achieve sustainable reductions in MP emissions.