Application of metal-organic frameworks for photocatalytic degradation of microplastics: Design, challenges, and scope

Microplastics (MPs), plastic particles smaller than 5 mm, are pervasive pollutants challenging wastewater treatment due to their size and hydrophobicity. They infiltrate freshwater, marine, and soil environments, posing ecological threats. In marine settings, MPs ingested by organisms cause cytokine release, cellular and DNA damage, and inflammation. As MPs enter the food chain and disrupt biological processes, their degradation is crucial. While biodegradation, pyrolysis, and chemical methods have been extensively studied, the use of metal-organic frameworks (MOFs) for MP pollution mitigation is underexplored. In this study, we explored the photocatalytic degradation mechanisms of MPs by MOFs in aquatic environments. We analyzed the hydrolysis, oxidation, and adsorption processes, while focusing on the environmentally friendly and cost-effective photocatalytic approach. Additionally, we analyzed the literature on MP decomposition for various types of MOFs, providing a detailed understanding of the degradation mechanisms specific to each MOF. Furthermore, we evaluated the degradation efficiencies of different MOFs and discussed the challenges and limitations in their application. Our study highlights the need for an integrated approach that involves the application of MOFs while considering environmental factors and safety concerns to develop effective MP degradation models. This review provides a framework for developing reliable photocatalytic materials with high MP removal and degradation efficiencies, thereby promoting the use of MOFs for marine plastic pollution mitigation.