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Mechanistic insights into the co-transport of microplastic degradation products in saturated porous media: The key role of microplastics-derived DOM

The Science of The Total Environment 2024 1 citation ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 35 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Kaixuan Sun, Xiaofeng Huo, Yanhong Zhang, Chen Zong, Chao Liu, Zhanxue Sun, Xiaoxia Yu, Peng Liao

Summary

Researchers investigated the co-transport of microplastic-derived dissolved organic matter (MP-DOM) and aged microplastics (AMPs) through saturated porous media under a range of environmentally relevant conditions. They found that as the degree of aging increased, changes in physicochemical characteristics of both AMPs and MP-DOM altered their transport behaviour, with MP-DOM playing a key role in the co-transport dynamics.

Microplastic-derived dissolved organic matter (MP-DOM) forms from the aging of microplastics (MPs), but the co-transport behavior of MP-DOM and aged MPs (AMPs) remains poorly understood. This study investigates the co-transport of AMPs and MP-DOM generated from original MPs (OMPs) over a wide range of environmentally relevant conditions. The transport of AMPs and MP-DOM changes as the degree of aging increases, specifically related to changes in their physicochemical characteristics. Results showed that the order of migration ability was MP-DOM > AMPs > OMPs under almost all tested conditions. The change of hydrophobicity of MP-DOM and AMPs, as well as small molecular weight of MP-DOM, was primarily responsible for this order. The role of MP-DOM as a degradation product in the co-transport process is notably significant under various environmental conditions because of its high mobility and organic carbon fraction within the system. Furthermore, it is important to note that MP-DOM affected the transport of MPs through a combination of positive and negative effects. Key mechanisms include electrostatic repulsion caused by protonation reactions triggered by the acidic pH of MP-DOM, steric hindrance, and competition for retention sites on media surfaces. This study contributes to a deeper understanding of the transformation and fate of MPs in complex environmental systems.

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