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Application of Magnetic Biochar@Alginate Composite as Adsorbent for Effective Removal of Methylene Blue from Aqueous Media

The Eurasia Proceedings of Science Technology Engineering and Mathematics 2024 1 citation ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 35 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Şerife Parlayıcı, Erol PEHLIVAN

Summary

Researchers synthesized a magnetic biochar-alginate composite (mBC@Alg) adsorbent for methylene blue removal from aqueous solutions, characterizing it via FTIR and SEM, and determining through batch adsorption experiments that the material follows Langmuir isotherm behavior with a maximum adsorption capacity of 416.67 mg/g and fits a pseudo-second-order kinetic model.

In recent years, magnetic biochar has been widely used for the removal of dyes in polluted water due to its magnetic separation abilities and has been used as composite adsorbents by incorporating different biomasses into its structure for the removal of such pollutants. In this study, a new composite magnetic biochar@alginate composite (mBC@Alg) was synthesized as an alternative adsorbent for the removal of methylene blue (MB) from aqueous solutions. The primary focus of this intensive preparation procedure is on the synthesis, characterization, and optimization of the mBC@Alg for enhanced MB adsorption capacity. The composite material was characterized using FT-IR analysis and scanning electron microscopy (SEM). Batch adsorption studies experiments were performed to determine the removal efficiencies, pH, adsorbent dose, contact time and initial concentration of MB molecules. Various adsorption isotherms such as Freundlich, Langmuir, Scathard and Dubinin-Radushkevich were used to describe the adsorption behavior at equilibrium. The Langmuir adsorption isotherm was identified as the most appropriate model to explain the observed adsorption phenomena, and the adsorption capacity of mBC@Alg for MB was determined to be 416.67 mg/g using this isotherm. Kinetic studies were carried out using pseudo-first-order and pseudo-second-order kinetic models and it was concluded that the experimental data fit well with the second-order kinetic model. The adsorbent properties of the mBC@Alg composite are particularly effective in removing MB molecules from aqueous solutions.

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