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Enhancing the Removal of Diethylhexyl Phthalatefrom Secondary Effluent Using Guar Gum
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Guar gum was tested as a natural biopolymer coagulant to remove diethylhexyl phthalate (DEHP) from secondary wastewater effluent, achieving 54.84% COD removal and ~92% turbidity removal at just 3 mg/L—comparable to or better than conventional alum treatment.
With the increasing global concern about environmental issues, researchers are increasingly interested in the use of natural biopolymers to replace inorganic coagulants in order to reduce the use of inorganic coagulants.The removal of diethylhexyl phthalate (DEHP) from secondary effluent by guar gum was investigated and compared with that of alum.Guar gum effectively removed approximately 92.11% of turbidity, 71.47% of total phosphorus, and 54.84% of chemical oxygen demand at a dosage of 3 mg L -1 .Further, evaluation and optimization of reaction conditions of coagulation-flocculation process in wastewater treatment by Box-Behnken design of Response Surface Methodology (RSM).The results indicated that a guar gum dosage of 3 mg L -1 at pH=7 resulted in the removal of 78.93% of DEHP.SEM showed that guar gum produces flocs with many voids in them compared with alum.This illustrates the greater availability of guar gum in catching and removing particles in suspension and DEHP compared with alum.FTIR indicated that organic matter in the effluent had chemically attached to the coagulants, leading to the removal of the organic matter.Given its nontoxicity and biodegradability, guar gum demonstrates promising potential as a coagulant in wastewater treatment.
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Researchers found that combining alum with tamarind seed extract as a natural coagulant aid removed up to 98.8% of polyamide microplastics from diverse water matrices — including river, lake, tap, and wastewater — through charge neutralization, adsorption bridging, and sweep flocculation, following second-order Brownian coagulation kinetics.
Flocculation Properties of Acrylamide‐Grafted Tamarind Polysaccharide on Microplastics and Heavy Metals Ions
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Researchers created a modified polysaccharide derived from tamarind — a natural plant material — that acts as an effective flocculant, clumping together PVC microplastics and lead ions from water so they can be removed. Under optimized conditions, the material removed over 91% of PVC microplastics and over 93% of lead ions, with even better performance when both contaminants were present together. This bio-based flocculant offers a sustainable option for treating water contaminated with both microplastics and heavy metals simultaneously.
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Researchers tested coagulation as a method to remove microplastics from tap water, evaluating how microplastic type (PE and PVC), water pH, coagulant dose, and microplastic concentration affect removal efficiency, and finding that detergent-assisted coagulation improves performance.
Enhancing the remediation of polyamide microplastics: A comparative study of natural and synthetic coagulants
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Researchers compared natural plant-based coagulants with the synthetic coagulant alum for removing polyamide microplastics from water. They found that alum was more effective overall, removing up to 94% of microplastics, while the natural coagulants achieved moderate removal rates and worked best with larger particles. The study suggests that coagulation-based water treatment can meaningfully reduce microplastic contamination, with natural alternatives offering a more sustainable option.
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