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Enhanced Capacitive Performance of Microwave-Driven CNTs on Carbonized Cigarette Filter Waste for Sustainable Energy Storage

Nanomaterials 2025 1 citation ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count.
Young Joong Choi, Damin Lee, Se‐Hun Kwon, Kwang Ho Kim

Summary

This study repurposed cigarette filter waste — a major source of microplastic pollution — by converting it into a high-performance material for energy storage. Researchers grew carbon nanotubes on carbonized cigarette filter powder using a microwave process, creating an electrode that stored energy with impressive efficiency and retained over 96% of its capacity after 5,000 charge cycles. The approach turns a persistent plastic pollutant into a useful material, offering a creative recycling pathway for one of the world's most littered items.

Microplastic pollution represents a significant global environmental issue, with cigarette filters being a major contributor due to their slow biodegradation. To address this issue while creating valuable materials, we developed a novel approach to synthesize nitrogen-doped carbon nanotubes on carbonized cigarette filter powder (NCNT@cCFP) using a microwave irradiation and nickel-catalyzed process. The successful incorporation of nitrogen (~6.6 at.%) and the enhanced graphitic structure create a hierarchical conductive network with abundant active sites for electrochemical reactions. The resulting NCNT@cCFP electrode exhibits a specific capacitance of 452 F/g at 1 A/g in a three-electrode configuration. The integrated hierarchical structure facilitates efficient electron transport and ion diffusion, leading to excellent rate capability (91.6% at 10 A/g) and cycling stability (96.5% retention after 5000 cycles). Furthermore, a symmetric supercapacitor device demonstrates promising energy storage capability with a maximum energy density of 14.0 Wh/kg at 483.1 W/kg, while maintaining 10.4 Wh/kg at a high power density of 4419.1 W/kg. This synergistic waste recycling strategy combined with microwave-driven synthesis offers a sustainable pathway for developing high-performance energy storage materials.

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