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Analytical approaches to track nylon 6 microplastic fiber degradation using HKUST-1(Cu/Fe)-derived CuO/TiO2 photocatalyst
Summary
Researchers developed a new photocatalyst derived from copper and iron compounds that can break down nylon 6 microplastic fibers using light. The material successfully degraded the nylon by oxidizing and breaking its polymer chains, producing smaller soluble organic compounds as byproducts. The study demonstrates a promising light-driven approach to degrading one of the most common types of microplastic fibers found in the environment.
Nylon 6 microplastic (MP) degradation was performed for the first time by photocatalysis using HKUST-1(Cu/Fe)-derived CuO/TiO 2 (TCFH). The TCFH composites with 5, 10, and 15 wt % of HKUST-1(Cu/Fe) were synthesized using the solvothermal method , followed by calcination , and deposited on borosilicate glass . The prepared materials were analyzed using TGA/DSC, UV–Vis/DRS, PL spectroscopy, XRD , XPS, FTIR, N 2 physisorption , and SEM-EDS techniques to confirm their crystallinity , chemical bonding, porosity, thermal, optical, and morphological properties. With an increase in HKUST-1(Cu/Fe) content in TiO 2 , the crystallite size, surface area , and pore size increased, whereas the bandgap energy and the recombination rate of photogenerated e − /h + pairs decreased compared to TiO 2 , favoring nylon 6 MP degradation. The TCFH (15 wt %) displayed optimal MP degradation performance, degrading MPs at pH 7 under UV–Vis light, showing an increase in TOC content during MP degradation (11.42 mg L −1 ), related to the presence of soluble by-products, a decrease in turbidity associated with the reduction in particle size and MP concentration, and a decrease in amide signal intensity at 3090 cm −1 compared with values observed during photolysis and TiO 2 photocatalysis . SEM and XPS analyses confirmed the oxidation and breakage of the MP polymeric chain. Soluble organic compounds such as aldehydes, amides, and carboxylic acids generated during MP degradation were detected by GC–MS. Thus, photocatalysis using the bimetallic MOF HKUST-1(Cu/Fe)-derived CuO/TiO 2 is a promising treatment for eliminating polyamide MPs in water effluents, where reactive oxygen species ( • OH and O 2 − ) contribute to their degradation. • Bimetallic HKUST-1(Cu/Fe)-derived CuO/TiO 2 was synthesized by solvothermal/calcination method. • CuO/TiO 2 showed large surface area, visible response, and retarded recombination. • Incorporating 15%wt (Cu/Fe) HKUST-1 in TiO 2 favors nylon 6 MPs degradation at pH 7. • Cavity formation and water-soluble by-product generation evidenced MP oxidation. • • OH and O 2 − species contributed in CuO/TiO 2 mediated photocatalytic degradation.