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Controlling Small Particles for Two-Step Density Sorting of Simulated Microplastics: Overcoming Surface Tension Effects with Surfactants

Environment and Natural Resources Journal 2025 Score: 38 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Md. Ariful Islam, Shamim Al Mamun, Kei NAKAGAWA, Ken‐ichi Shimizu, Mitsuharu Yagi, Achara Ussawarujikulchai, Hiroshi Asakura

Summary

Researchers developed a two-step density-based floatation sorting protocol for separating simulated microplastics from sediment samples, addressing the challenge of surface tension effects that cause particles to float regardless of density. By applying surfactants to overcome surface tension, the method provides a lower-cost alternative to infrared spectrometry for estimating the ratio of floating to sinking microplastics in environmental samples.

Study Type Environmental

Infrared spectrometers are commonly recommended for analyzing microplastics (MPs) in sediment samples. However, these instruments are costly and time consuming, limiting the scope of surveys and our understanding of the distribution and long-term variation of MPs. Although it is challenging to determine MPs by floatation sorting, it is possible to estimate the ratio of MPs that float and sink in seawater. The study employed floatation sorting to confirm whether MPs with densities lower than the liquid float and those with densities higher sink, even for MPs smaller than 1 mm. As expected, large MPs (1 to 4.75 mm in size) with densities higher than that of the liquid sank. Unexpectedly, small MPs (212 μm to 1 mm) with densities higher than the liquid’s density also floated. Assuming the unexpected floating was due to surface tension, we added a surfactant to lower it, causing MPs with densities higher than the liquid’s to either sink as expected or accelerate sinking. Thus, with the use of a surfactant, even small MPs can be sorted by density if a heavy liquid is used after water.

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