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Fouling behavior of nano/microplastics and COD, TOC, and TN removal in MBR: A comparative study
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This study tested a membrane bioreactor (MBR) — a combination of biological treatment and membrane filtration used in wastewater plants — for its ability to remove nano- and microplastics from wastewater. The system achieved 99.4% removal of organic pollutants and complete removal of nanoplastics, and found that more hydrophilic membranes were better at capturing microplastics. The study also examined how microplastics foul and clog membranes over time, which is a practical challenge for wastewater treatment operations. These results support MBRs as a promising technology for reducing microplastic discharges from treatment plants into waterways.
The global upsurge in plastic demand has overwhelmed waste management systems, with nano/microplastic (N/MP) pollution emerging as a critical environmental challenge. With wastewater treatment plants (WWTPs) identified as a key source of MPs release to the aquatic environment, reflecting the design limitations in addressing MPs. Herein, this comparative study proposes a novel application of a complete mixed anoxic-oxidation membrane bioreactor (MBR) integrated with three varying polyvinylidene fluoride (PVDF) hollow fiber (HF) membranes for N/MP removal. The fouling behavior of MPs within the MBR was investigated to provide insight on the NPs rejection capabilities of the MBR. The results demonstrate high organics rejection efficiency (99.43% ± 0.13%), complete removal of NPs, and a direct correlation between membrane hydrophilicity and fouling resistance. Notably, hydrophilic and smooth membranes promoted the interaction of microbial aggregation and agglomerations of NPs, enhancing their capture. This study highlights the pivotal mechanism and role of membrane selection in optimizing MBR as an adaptable and effective solution for mitigating N/MPs pollution in wastewater. PRACTITIONER POINTS: Microplastics pollution in membrane bioreactor. Fouling mechanism of microplastics in membrane bioreactor. Fouling behavior of microplastics in membrane bioreactor. Interaction of microplastics and membrane bioreactor. Fouling resistance of microplastics in membrane bioreactor.
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Researchers simulated the long-term accumulation of polypropylene microplastics in membrane bioreactors used for wastewater treatment. They found that while microplastic accumulation did not reduce the removal of key pollutants like COD and ammonia nitrogen, it did increase membrane fouling and alter the composition of microbial communities in the reactor. The study suggests that microplastic buildup in wastewater treatment systems may affect operational efficiency over time.
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Researchers reviewed recent advances in understanding how micro- and nanoplastics contribute to membrane fouling during water treatment processes. The study found that while membrane separation effectively removes microplastics from wastewater effluent, fouling caused by plastic particles along with dissolved organics and extracellular polymers remains a key obstacle, and understanding the fouling mechanisms is critical for improving treatment efficiency.
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