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Biodegradable CA-based nanofiber membranes with ZnO/SnO2 heterojunctions for efficient emulsion separation and photocatalytic self-cleaning

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Researchers created a biodegradable fiber membrane, made from treated cellulose and metal oxide coatings, that separates oil from water with high efficiency and can self-clean under UV light. In lab tests, the membrane broke down into small fragments when exposed to an enzyme solution, suggesting it would not leave behind long-lasting microplastic waste after disposal.

Study Type Environmental

Organic pollutant-induced membrane failure and microplastic accumulation derived from discarded spent membranes pose severe obstacles to the sustainable development of oil/water (O/W) separation membrane technology. In this study, a self-cleaning and biodegradable deacetylated cellulose acetate nanofiber membrane modified with ZnO/SnO 2 heterojunctions (d-CA@ZnO/SnO 2 ) was fabricated by electrospinning and deacetylation process. Simultaneous stripping removal of acetyl groups and polyvinylpyrrolidone fillers effectively enhanced the surface roughness of the membrane, which greatly improved its hydrophilicity and underwater oleophobicity. Benefiting from such favorable surface properties, the d-CA@ZnO/SnO 2 membrane exhibited outstanding separation performance for various O/W emulsions, resulting in the higher permeation flux (∼ 972.25 L·m −2 ·h −1 ) and separation efficiency (∼ 98.2%). Due to the staggered band alignment of ZnO/SnO 2 heterostructures, the charge carrier recombination was prominently suppressed, which allowed the membrane to achieve an exceptional photocatalytic self-cleaning efficiency with a flux recovery rate exceeding 95% via ultraviolet-driven active photodegradation of organic foulants. Meanwhile, enzymatic degradation tests confirmed that the discarded membrane could be disintegrated into fine fragments within cellulase solutions, which presented a practical and eco-friendly approach for oily wastewater purification without causing secondary microplastic pollution.

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