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Sustainable photocatalytic CO2 conversion using microalgae as a carbon-negative scavenger

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Scientists developed a new material that uses sunlight to turn CO2 into usable fuel gases, and found that adding microalgae (tiny water plants) to the process dramatically boosts how much CO2 gets converted—up to 10 times more than without it. This matters because it offers a "win-win" climate solution: the algae soak up CO2 through photosynthesis while helping the reaction work better, pointing toward a more efficient, eco-friendly way to fight climate change without relying on microplastics or other less sustainable materials.

Photocatalytic CO2 conversion driven by solar energy is a highly promising approach in addressing rising atmospheric CO2 levels; however, its practical application remains limited by low conversion efficiency. In this study, a new strategy to enhance CO2 reduction toward CO and CH4 is proposed through the employment of microalgae as a sacrificial agent, and the efficiency is compared with conventional CO2 conversion without and with the use of microplastics as sacrificial agents. To realize this strategy, an AB2O6-type high-entropy oxide (HEO), (Cs1/7Ba4/7Bi2/7)(Nb1/2Ta1/2)2O6, with bi-polymorphy of layered perovskite and pyrochlore, is rationally designed. The HEO incorporates alkali metal cesium and alkaline earth metal barium to increase surface basicity for CO2 chemisorption, bismuth with its stereochemically active lone pairs for localized polarization and charge separation, and tantalum and niobium to form octahedral crystalline frameworks for charge transport. The utilization of microalgae during photocatalytic reactions leads to a remarkable enhancement in CO2 conversion compared to catalysis with or without using microplastics, with CO and CH4 production increasing by 10- and 4-fold, respectively, compared to the system using only HEO. These findings not only demonstrate a new family of polymorphic AB2-type HEOs for photocatalysis but also show the potential of microalgae as a sustainable sacrificial agent, offering an environmentally friendly pathway for efficient CO2 capture (through photosynthesis by microalgae) and CO2 conversion (through photocatalysis by HEOs).

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