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Extraction and determination of microplastics and associated PAHs in seawater and beach sediments from the northwestern part of the Caspian Sea

Analytical Methods in Environmental Chemistry Journal 2025 3 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 48 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Olga Kuznetsova

Summary

Researchers collected microplastics and beach sediments from the northwestern Caspian Sea and used GC-MS to characterize polycyclic aromatic hydrocarbons adsorbed on the MPs, finding PAH profiles consistent with petroleum combustion sources and documenting MP-PAH co-contamination in this landlocked sea.

Study Type Environmental

The adsorption of persistent organic pollutants (POPs) on microplastics (MPs) in the marine environment is a pressing issue. This study, which focused on the northwestern part of the Caspian Sea, aimed to assess the extent of MP pollution and investigate the origin of polycyclic aromatic hydrocarbons (PAHs) adsorbed on MPs isolated from seawater and coastal sediments. In this study, gas chromatography-mass spectrometry (GC–MS) measured the amount of PAHs. Detection limits were 0.1–1.3 ng g-1. Recovery experiments were conducted in 5 replicates at two concentration levels, 5 and 25 ng g-1. The recovery of standards was from 80.2 ± 5.2% to 99.1 ± 4.9%. The study also considered the relationship between PAH content and the size of the MPs. The concentration of Σ16PAHs at all investigated sampling sites ranged from 97.6 to 210.5 ng g-1 and from 93.9 to 332.3 ng g-1 in MPs from seawater and beach sediments, respectively. Notably, the study found that for MPs of 0.1 to 1 mm in size, the PAH concentrations determined by GC-MS were, on average, 20–40% higher than for 3–5 mm MPs. The concentration of PAHs in the northwestern part of the Caspian Sea was found to be lower than in the southern part, as indicated by our results, underscoring the significance of this study’s findings.

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